The synthesi̇s and properti̇es of transi̇ti̇on metal complexes wi̇th i̇mi̇dazoli̇di̇n-2-yli̇dene li̇gand
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Abstract (EN)
Inthisstudy, 1,3-dialkylimidazolinium chloride salts, silver(I)-N-heterocycliccarbene and ruthenium(II)-N-heterocyclic carbene complexesweresynthesized. The structure of allsynthesizedcompoundsweredeterminedbyusingspectroscopictechniquessuch as 1H-NMR, 13C-NMR, IR andelementalanalyses.Thestructure of a Ru(II)–NHC complexwasalsoexplainedby X-Ray singlecrystalmethod. Enzymeinhibitioneffects of imidazolinium salts on -carbonicanhydraseisoenzymes, AChE, BChEand α-Glycosidaseenzymeswereinvestigated. ThesynthesizedRu(II)-NHC complexeswereused as catalysts in the transfer hydrogenation of arylketones and correspondingsecondaryalcoholswasobtainedwithgoodyields.
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Yılmaz Işık
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Yılmaz Işık (Master Thesis). The synthesi̇s and properti̇es of transi̇ti̇on metal complexes wi̇th i̇mi̇dazoli̇di̇n-2-yli̇dene li̇gand, 2019, Adıyaman University.
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