The determination of the magnetic susceptibility and the stability constant of metal complexes of 1-(1h-benzoimidazol?2-yl)-ethanone thiosemicarbazone
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Abstract (EN)
In this research, the stability constants of metal complexes of previously synthesised [1-(1H-Benzimidazol-2-yl)-Ethanone Tiosemicarbozone ligand were determined and their magnetic measurements were performed. The stability constants of the metal complexes were determined by using a spectroskopic method (Job).For a given ligand the stability constanf of complexes with metal ions follows the order: Fe2+ < Co3+ < Ni2+ < Cu2+ > Zn2+. This order matches Irving-Williams series of stability.The number of unpair electrons (n) on the metal for each complex was also calculated using relevant equations.It was found that Zn2+, Fe2+ and Co3+ complexes are diamagnetic and Ni2+ and Cu2+ complexes are paramagnetic.2008, 62 pagesKeywords: Thiosemicarbazone, Metal Complex, Magnetic Susceptibility, Stability Constant
Author
İbrahim Kopan
Institution
How to Cite
İbrahim Kopan (Master Thesis). The determination of the magnetic susceptibility and the stability constant of metal complexes of 1-(1h-benzoimidazol?2-yl)-ethanone thiosemicarbazone, 2008, Afyon Kocatepe University, Kimya Bölümü.
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