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The synthesis and characterization of some cyclicphosphazenes and their polymers

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2004
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Abstract (EN)

ABSTRACTIn this work some monoamines and sodium salts of bisphenols were interactedwith hexachlorocyclotriphosphazene (Trimer, N3P3Cl6) in acetonitrile. Mono, di andfullysubstituted phosphazene compounds were obtained as a result of one-step reaction.Poly(dichloro)phosphazene was synthesised from the thermal polymerization reactionof hexachlorocyclotriphosphazene. Polybis(amino) phosphazenes were obtained fromthe substitution reaction of the poly(dichloro)phosphazene with some monoamines, inTHF.The structure of the synthesised phosphazene compounds and polymers wereenlightened using data obtained from IR, 1H-, 13 31C-, P-NMR, MS, TGA, DTA andHPLC spectrums. The antimicrobial properties of the new phosphazenes andpolybis(amino)phosphazenes were investigated.Keywords: Polyphosphazene, Aminophosphazene, Spectroscopic Data,Antimicrobial Activity.II

Author

Sevinç Yılmaz

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Sevinç Yılmaz (Master Thesis). The synthesis and characterization of some cyclicphosphazenes and their polymers, 2004, Çanakkale Onsekiz Mart University.

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