The synthesis of substıtue cyclophosphazenes and the spectroscopic investigation of their structures

Hazırlanan bu Yüksek Lisans tezi BAP tarafından 2005 / 29 no'lu projeden desteklenmiştir.THE SYNTHESIS OF SUBSTITUE CYCLOPHOSPHAZENES AND THESPECTROSCOPIC INVESTIGATION OF THEIR STRUCTURESABSTRACTIn this work sodium salt of 2,2?-methylenebis(4-chlorophenol) was interacted withhexachlorocyclotriphosphazene in tetrahydrofurane. Disubstituted phenoxy (2, 3) phosphazenecompounds were synthesized. Geminal-bis(ter-butylamino) phenoxyphosphazene compounds (4, 5)were synthesized from the reaction of excess tert-butylamine with disubstituted phenoxy phosphazene(2, 3) in tetrahydrofurane.The structure of the synthesized phosphazene compounds were identified using data1 13 31obtained from IR, H-, C-, P-NMR and MS spectroscopy. The structure of the compound 2 wasalso identified by using the X-ray crystallography method.Keywords: Hexachlorocyclotriphosphazene, Phenoxy phosphazene, Geminal phosphazene,Spectroscopy, X-ray crystallography