Synthesis of functionalized metal organic frameworks by increasing the basicity, characterization and use as catalysts in the knoevenagel reactions
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Abstract (EN)
In this study, Cr based metal organic frameworks (MIL-101) were synthesized by solvothermal method. The basicity of these synthesized catalysts were increased with ethylenediamine as organic solvent and different eutectic solvents (DES) and their application as catalyst was investigated. The characterization of raw and functionalized Cr based metal organic frameworks was performed by different techniques and the effect of functionalization on the structure of metal organic frameworks was highlighted. The catalytic activities of functionalized metal organic frameworks were tested in Knoevenagel reaction occurring between benzaldehyde and malononitrile. The effects of parameters such as reactant ratio, temperature, and amount of catalyst, solvent type, reaction time, and catalyst type were investigated.
Author
Gökçe Anılır
How to Cite
Gökçe Anılır (Master Thesis). Synthesis of functionalized metal organic frameworks by increasing the basicity, characterization and use as catalysts in the knoevenagel reactions, 2018, Ege University.
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