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The Investigation of deamination reaction of including amines functional group of organic by free radical method

2002
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Advisor: Y.doç.dr. Şirin Gülten

Abstract (EN)

ABSTRACT Deamination reactions were applied to aromatic and aliphatic amines with free radical method. 4,4-Diaminobibenzyl, 4,4-diaminodiphenylether and 2-amino-6- methylheptane were chosen as starting materials. Amines were converted to isothiocyanates with DCC and CS2. The radical reaction was then applied to isothiocyanates with Bu3SnH and AIBN (2,2'- Azobis-(/so-bütironitril)) in benzene at 80 °C. Some products were identified by FT-IR, *H NMR, 13C NMR and mass spectrum. Keywords: Free radical, deamination, isothiocyanate, AIBN and BU3S1İH. «JSS* II

Author

Özgür Özay

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Özgür Özay (Master Thesis). The Investigation of deamination reaction of including amines functional group of organic by free radical method, 2002, Çanakkale Onsekiz Mart University.

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