Synthesis and characterization, of vic-dioximes derivatives and investigation of some of its transition metal complexes

in ABSTRACT MASTER THESIS SYNTHESIS AND CHARACTERIZATION, OF K/C-DIOX1MES DERIVATIVES AND INVESTIGATION OF SOME OF ITS TRANSITION METAL COMPLEXES Erdal CANPOLAT Fırat University Graduate School of Natural and Applied Sciences Department of Chemistry 1999, Page:37 \ In this work one new ligand and its transition metal complexes were synthesized. In | the work performed, l,2-o-izopropilidene-4-aza-6-amino hexane (R1NH2) was reacted with I anti-mono chloro glyoxime to obtain 1.2-di (hydroxyimino)-3.6-di aza-8. 9-o- 6 I izopropilidene nonane (LiH2) ligand was synthesized. Mono nuclear complexes ot this I I ligand having a metal ligand ratio of 1:2 were prepared with Ni (II), Co (II), Cu (II). f I Finally UO2 (VI) complex of this ligand was synthesized. \ In conclusion, one ligand and four compiexes were svnthesized and their structure I was determined with IR, lH-NMR, 13C-NMR spectroscopy, magnetic susceptibility and I I elemental analyses. Properties of ligands and their complexes, were obtained using TGA I I technique. I Attempt to prepare the (L2H;) and its homo trinuclear and heterotrinuclear complexes were failed. Keywords: 1,3-dioxolane amine, Vic-dioximes. Vic-dioximes of complexes.