Synthesis of solid supported phosphine ligands and their metal complexes
2008
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Advisor: Prof. Dr. Osman Serindağ
Abstract (EN)
[N,N-bis(diphenylphosphinomethyl)aminopropyltrietoxysilane] ligand was synthesized and supported to the silica, and its Ni(II), Co(II), Pt(II), Pd(II), Rh(I), Ru(II), Au(I) complexes were synthesized by Schlenk Technique under nitrogen atmosphere. All aminometylphosphine ligands and their metal complexes were characterized using atomic absorption, FT-IR, 1H, 13C, 31P NMR spectrophometers and microanalytical method.For catalytic reaction; styrene, nitrobenzene, benzaldehyde and cinnamaldehyde were tested by hydrogenation method. Transfer hydrogenation of acetophenon was investigated by using Ru(II) catalyst. Also Pd(II) catalysts was tested in Heck reaction between metylacrylate and iodobenzene compounds.
Author
Mustafa Keleş
Institution
How to Cite
Mustafa Keleş (Doctorate thesis). Synthesis of solid supported phosphine ligands and their metal complexes, 2008, Çukurova University, Kimya Bölümü.
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