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Comparasion of nitro aromatic compounds oxidation by wet peroxide oxidation and electrooxidation

2006
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Advisor: Prof. Dr. İlyas Dehri

Abstract (EN)

ABSTRACTMS THESISCOMPARASION OF NITRO AROMATIC COMPOUNDS OXIDATIONBY WET PEROXIDE OXIDATION AND ELECTROOXIDATIONM.Burcu GİZİRDEPARTMENT OF CHEMISTRYISTITUTE OF NATURAL AND APPLIED SCIENCESUNIVERSITY OF CUKUROVASupervısor: Prof.Dr. İlyas DEHRİYear:2006 Page:57Jury: Prof.Dr. İlyas DEHRİProf.Dr. Mehmet ERBİLAsst.Prof..Dr. Nermin Şimşek KUŞThe oxidation efficiency of 2,4-dinitrotoluene and 4-nitrophenol which arehighly toxic and nonbiodegradable, compared by two methods wet peroxideoxidation and electrooxidation. Two parameters have been investigated during wetperoxide oxidation process, temperature and oxidant concentration (hydrogenperoxide). From concentration vs time graphic oxidation kinetics equation has beencreated. For wet peroxide oxidation reactions reactions degrees have been cahnged0.98-1,02. pH=12 and oxidation potential 1,8V values have been applied forelectroxidation experiments in existence of platinium electrodes. The obtained resultsfrom two methods have been compared. The results show us that wet peroxideoxidation much more effective than electrooxidation of nitroaromatics in highconcentration.Key words: Wet peroxide oxidation, electrooxidation, nitroaromatic compoundsII

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Münire Burcu Gizir

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Münire Burcu Gizir (Master Thesis). Comparasion of nitro aromatic compounds oxidation by wet peroxide oxidation and electrooxidation, 2006, Çukurova University.

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