Synthesis, characterization and copolymerization of new methacrylate monomer with piperonnyl group

In the first step of this study, 1,3-benzodioxol-5-methanamine was obtained with the compound chloroacetyl chloride in the solvent of dichloromethane from the recoil peaks which could affect the room. Then, by searching the products obtained, sodium methacrylate and acetonitrile solvent were reacted at 70-80ºC and displacement reactions were synthesized and intermittent monomer. The homopolymer of the MBAOM monomer was then synthesized in a glass vial under an atmosphere of nitrogen with an azobisisobutyronitrile (AIBN) initiator in a 1,4-dioxane solvent at a temperature of 65ºC. Copolymers of glycidyl methacrylate (GMA) and 2-[(methoxy-1,3-benzodioxol-5-yl) methanamine]-methacrylate (MBAOM) monomers were synthesized with the AIBN initiator and 1,4-dioxane solvent at 65ºC. The structures of monomers, homopolymers and copolymers, IR, 1H-NMR and 13C-NMR were included in the lectures. The monomer composition in the copolymer was determined by 1H-NMR analysis. Thermal behavior of homopolymers and copolymers, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) methods.