Synthesis of vic-dioxime derivative metal complexes and investigation of their metal deposition on carbon nanotubes

In this study, the oxime complexes are used as a precursor in the synthesis of carbon nanotube-supported metal nanoparticles were investigated. In the similar studies, the oxime complexes have not been used this field. For this purpose, vic-dioxime type fluorinated ligands; anti-[(4-trifluoromethyl)aniline] glyoxime (1), anti-[(4-perfluorooktil)aniline] glyoxime (2) and Cu(II) complexes of the fluorinated ligands(1),(2), 1,2-cyclohexanedione dioxime and dimethylglyoxime ligands Cu(II) complexes have been synthesized. Synthesized metal complexes have been used deposition of the metal nano-particles on the nanotubes. The synthesized fluorinated ligands and the metal complexes have been characterized by using 1H-NMR, 13C-NMR and FT-IR. These complexes used in the production of carbon nanotube-supported metallic nanoparticles. The carbon nanotube-supported metallic nanoparticles have been characterized by using XRD. Consequently, successful resuls were achieved with (anti-[(4-trifluoromethyl)aniline]glioksimato)bakır(II), Cu(1L)2; and (anti-[(4-perfluorooktil)aniline]glioksimato)bakır(II) complexes.