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Mathematical modelling of distribution coefficients of UO2(NO3)2-HNO3-TBP systems: Comparison with experimental data and literature

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Abstract (EN)

Understanding the distribution equilibria of uranyl nitrate and nitric acid between aqueous solution and tributyl phosphate (TBP) is important in order to determine the necessary data for extraction modeling of the PUREX process. Based on the distribution reactions, an empirical mathematical model and a MATLAB program have been developed to allow computer calculation of estimated distribution coefficients. For the 30 vol % TBP system, good agreement was shown between experimentally obtained distribution coefficients, values in the literature and the calculated coefficients.

Author

Emre Çağlak

How to Cite

Emre Çağlak (Master Thesis). Mathematical modelling of distribution coefficients of UO2(NO3)2-HNO3-TBP systems: Comparison with experimental data and literature, 2016, Ege University.

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