Synthesis, characterization and investigation of electrochemistry behaviour of novel metallo phthalocyanines with substituted triazole enviroment

Within the scope of this thesis, 4-(4-methyl-5-phenyl-4H-1,2,4-triazol-3-yl-thio) (3a) and 4-(4,5-diphenyl-4H- 1,2,4-triazol-3-yl-thio) (3b) substituted phthalonitrile compounds were synthesized in acetone medium and using triethylamine as base. Metallo-phthalocyanine molecules (4-9) were synthesized with the aid of substituted dinitrile derivative under nitrogen gas and in the presence of DMAE. Zn(CH3COO)2, CoCl2 and MnCl2 were used as metal salt. The structures of the new compounds obtained were illuminated by FTIR, 1H-NMR, 13C-NMR, UV-Vis and MS spectral data. The electrochemical properties of the synthesized metallo phthalocyanine compounds have been extensively studied.