Syntheses and characterization of new polymeric metal complexes and investigation of theirs catalytic effect and electrical properties

In this study, Aminomethylated polystyrene ligands P(S-DVB)Ll, P(S-DVB)L2, P(S-DVB)L3 and their Co(II), Fe(III),Cu(II),Ni(II) and Pd(II) metal complexes have been prepared and characterized by the spectroscopic and analytical techniques.The catalytic properties of P(S-DVB)Ll and P(S-DVB)L2 was researched by Suzuki Coupling reactions. All compounds have been characterized by elemental analyses, SEM-EDX, FT-IR, UV and TGA-DTA.The eletrical conductivity studies of the P(S-DVB)Ll, P(S-DVB)L2, P(S-DVB)L3 ligands and theirs metal complexes have been carried out. The resistivity values of all complexes are in semiconductor class. But, the resistivity of Pd-P(S-DVB)L3 is lower than the other complexes. In other words, the conductivity of this complex is higher than other complexes (107 times). In addition, it has been seen that all complexes have p-type semiconductor properties.