Application of chiral schiff bases of cu complexes in the asymmetric nitro aldol reactions
2007
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Advisor: Doç.dr. Nadir Demirel
Abstract (EN)
The nitroaldol reaction (or Henry reaction) is one of themost important and atom-economical reactions for carbon?carbon bond formation to generate bnitroalkanols. The diversity of the transformation of adducts, such as reduction to amines, Nef reaction to carbonyl compounds, or dehydration to nitroalkenes, offers avariety of applications for this reaction. Recent effortshave been focused on the development of catalytic enantioselective reaction variants. In these processes, differentchiral catalysts were developed, such as thosebased upon BINOL by Shibasaki, Bis(oxazoline) by Evans and Jørgensen, cinchona alkaloid by Corey, dinuclear zinc complexes by Trost, Salen?Co complexes by Yamada, and amino alcohols by Palomo.
Author
Dr. Mehmet Çolak
How to Cite
Mehmet Çolak (Master Thesis). Application of chiral schiff bases of cu complexes in the asymmetric nitro aldol reactions, 2007, Dicle University.
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